Cu₂O@β-cyclodextrin as a synergistic catalyst for hydroxyl radical generation and molecular recognitive destruction...

Wastewater systems contain a large number of compounds, such as anthropogenic aromatic pollutants and natural organic matter (NOM), and usually have pH higher than 4. Fenton-like reaction is the most widespread method for removal of organic pollutants, but their reactivity with H₂O₂ may be inhibited by NOM due to the competition of hydroxyl radicals and chelating agents. In this work, Cu₂O@β-cyclodextrin was developed to achieve the collaboration between molecular recognition and Fenton-like catalysis to destruct aromatic pollutants at neutral pH. In Cu₂O@β-CD, covalent CuOC bond was topotaxially converted from CuCl assisted by β-CD at room temperature. Covalently linked β-CD could keep humic acid from interfering catalytic performance of Cu₂O surfaces and inhibit the leaching of copper. A higher catalytic ability was observed for Cu₂O@β-CD with rate constant 0.0331 min^-1 than Cu₂O (0.0064 min^-1) at neutral pH. A mechanism of synergistic catalysis was proposed on the basis of Cu⁺, β-CD and phenoxo-Cu²⁺ complexes in the Cu₂O@β-CD/BPA/H₂O₂ system. The strategy of coupling molecular recognition into Fenton-like reaction provides an efficient and promising approach to the destruction of aromatic pollutants at neutral pH.