Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

30.9K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
30.9K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

48.6K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
48.6K
Band Theory02:35

Band Theory

17.3K
When two or more atoms come together to form a molecule, their atomic orbitals combine and molecular orbitals of distinct energies result. In a solid, there are a large number of atoms, and therefore a large number of atomic orbitals that may be combined into molecular orbitals. These groups of molecular orbitals are so closely placed together to form continuous regions of energies, known as the bands.
The energy difference between these bands is known as the band gap.
Conductor, Semiconductor,...
17.3K
Molecular Orbital Theory II03:51

Molecular Orbital Theory II

27.6K
Molecular Orbital Energy Diagrams
27.6K
Scientific Laws and Theories02:31

Scientific Laws and Theories

89.1K
Scientific Laws
89.1K
Valence Bond Theory02:42

Valence Bond Theory

11.3K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.3K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

The association between daily real-time assessment of subjective cognitive function and objective cognition using ecological momentary assessment.

Neuropsychology·2026
Same author

Promoting digital memory aid use in older adults with cognitive concerns: A pilot randomized controlled trial of adaptive web-based training.

Neuropsychology·2026
Same author

Examining intra-individual variability of ecological momentary assessment with multilevel modeling: A systematic review and recommendations for research and practice.

The Clinical neuropsychologist·2025
Same author

Corrigendum to "Obesity as a moderator of lumbar spine posture change during pregnancy" [Gait Posture 122 (2025) 320-325].

Gait & posture·2025
Same author

Obesity as a moderator of lumber spine posture change during pregnancy.

Gait & posture·2025
Same author

Cutoffs of the Instrumental Activities of Daily Living-Compensation (IADL-C) Scale for Identification of Functional Limitations Consistent With Mild Cognitive Impairment and Dementia.

Archives of clinical neuropsychology : the official journal of the National Academy of Neuropsychologists·2025
Same journal

General formulae for transforming Pearson's r to the scale of Cohen's d.

Applied psychological measurement·2026
Same journal

babebi: An R Package for Bayesian Estimation and Validation in Small-N Two-Rater Pre-Post Designs.

Applied psychological measurement·2026
Same journal

A Tool for Agreement and Alignment Analysis in Binary Rating Tasks: The R Package scindex.

Applied psychological measurement·2026
Same journal

The EM Algorithm and Its Variants in Cognitive Diagnostic Models: Comparing Their Propensity for Boundaries, Extremes, Convergence, and Suboptimal Solutions.

Applied psychological measurement·2026
Same journal

When Perceptions of Social Desirability Differ: Implications for the Multidimensional Nominal Response Model of Faking.

Applied psychological measurement·2026
Same journal

csemGT: An R Package for Estimating Raw-Score Conditional Standard Errors of Measurement in Generalizability Theory.

Applied psychological measurement·2026
See all related articles

Related Experiment Video

Updated: Feb 9, 2026

Databases to Efficiently Manage Medium Sized, Low Velocity, Multidimensional Data in Tissue Engineering
09:43

Databases to Efficiently Manage Medium Sized, Low Velocity, Multidimensional Data in Tissue Engineering

Published on: November 22, 2019

6.8K

Parameter Recovery in Multidimensional Item Response Theory Models Under Complexity and Nonnormality.

Dubravka Svetina1, Arturo Valdivia1, Stephanie Underhill1

  • 1Indiana University, Bloomington, IN, USA.

Applied Psychological Measurement
|June 9, 2018
PubMed
Summary
This summary is machine-generated.

Multidimensional item response theory (MIRT) parameter recovery is negatively impacted by skewed latent trait distributions and complex item structures. These factors reduce the accuracy and precision of psychometric item property estimation in assessments.

Keywords:
complex structuremultidimensional IRTnonnormalityparameter estimation recovery

More Related Videos

Multidimensional Coculture System to Model Lung Squamous Carcinoma Progression
07:53

Multidimensional Coculture System to Model Lung Squamous Carcinoma Progression

Published on: March 17, 2020

7.7K
Analysis of Multidimensional Microscopy Data Using Cell-ACDC
06:17

Analysis of Multidimensional Microscopy Data Using Cell-ACDC

Published on: November 7, 2025

553

Related Experiment Videos

Last Updated: Feb 9, 2026

Databases to Efficiently Manage Medium Sized, Low Velocity, Multidimensional Data in Tissue Engineering
09:43

Databases to Efficiently Manage Medium Sized, Low Velocity, Multidimensional Data in Tissue Engineering

Published on: November 22, 2019

6.8K
Multidimensional Coculture System to Model Lung Squamous Carcinoma Progression
07:53

Multidimensional Coculture System to Model Lung Squamous Carcinoma Progression

Published on: March 17, 2020

7.7K
Analysis of Multidimensional Microscopy Data Using Cell-ACDC
06:17

Analysis of Multidimensional Microscopy Data Using Cell-ACDC

Published on: November 7, 2025

553

Area of Science:

  • Psychometrics
  • Educational Measurement
  • Psychological Statistics

Background:

  • Item parameter recovery is crucial for robust assessment development, particularly in item response theory (IRT).
  • Existing research extensively covers unidimensional IRT parameter recovery, but less is known about multidimensional IRT (MIRT), especially with complex test structures or non-normal latent traits.
  • Understanding parameter recovery in MIRT is vital for advanced applications like computerized adaptive testing.

Purpose of the Study:

  • To investigate the impact of complex item structures and non-normal latent trait distributions on item parameter recovery in compensatory MIRT models.
  • To evaluate the effects on bias and root mean square error of item parameter estimates.
  • To provide insights into the reliability of MIRT parameter estimation under challenging conditions.

Main Methods:

  • A simulation study was conducted using compensatory MIRT models for dichotomous items.
  • Complex item structures and skewed latent trait distributions were systematically manipulated.
  • Item parameter recovery was assessed using bias and root mean square error as outcome variables.

Main Results:

  • Skewed latent trait distributions generally led to adverse impacts on item parameter recovery.
  • Increased test complexity further decreased the precision of parameter recovery.
  • Discrimination parameters, particularly along one dimension, were notably affected when at least one latent trait was skewed.

Conclusions:

  • The findings highlight the sensitivity of MIRT parameter recovery to the shape of latent trait distributions and test complexity.
  • Assessment developers should exercise caution when interpreting MIRT parameters derived from data with non-normal latent traits or complex structures.
  • Further research is needed to develop robust methods for parameter recovery in MIRT under these conditions.