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Published on: September 18, 2018
Levels, dietary intake and risk of polybrominated diphenyl ethers (PBDEs) in foods commonly consumed in Nigeria
1Department of Chemistry, University of Ibadan, Ibadan, Oyo State, Nigeria; Basel Convention Coordinating Centre for Training and Technology Transfer for Africa Region, University of Ibadan, Ibadan, Oyo State, Nigeria.
Abstract:
Polybrominated diphenyl ethers are non-reactive flame retardants listed among the persistent organic pollutants. This study assesses the levels and health risk of PBDEs in foods commonly consumed by the adult population in Southwest Nigeria. Eight different food categories were collected and extracted using standard QuEChERS protocol prior to analysis by gas chromatography with micro electron capture detector. Aquatic foods had the highest maximum concentration of the eight PBDEs congeners, 748 pg/g; followed by 80.3 pg/g and 54.9 pg/g in edible oil and meat products, respectively. Dairy products had the lowest concentration (0.46 pg/g). The estimated average dietary intake of PBDEs by an adult was 131 pg/kg bw/day. Based on the levels of PBDEs found in common foods consumed by the adult population in Southwest Nigeria, there is unlikely to be a health risk. However, there is a need to investigate the dietary intake of PBDEs in other food categories, especially by vulnerable groups, such as children and the elderly.
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Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
Common Ion Effect
Crown Ethers

