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Updated: Feb 9, 2026

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
Published on: February 10, 2023
Core-Shell Crystals of Porous Organic Cages
Shan Jiang1, Yi Du2, Marco Marcello3
1Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
Abstract:
The first examples of core-shell porous molecular crystals are described. The physical properties of the core-shell crystals, such as surface hydrophobicity, CO2 /CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core-shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules.
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