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Vertical Curve: Problem Solving01:23

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Vertical curves provide the transition between two roadway grades, ensuring safety, comfort, and functionality. Calculating elevations at specific stations along the curve involves several systematic steps based on the curve's geometry and provided design parameters.The vertical curve is defined by its length, grades, Point of Vertical Intersection (P.V.I.) location, and P.V.I. elevation. The stations of the Point of Vertical Curvature (P.V.C.), where the curve begins, and the Point of Vertical...
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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
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Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
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Introduction to Vertical Curves01:24

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Vertical curves are parabolic transitions that connect different grades on highways and railroads, ensuring a smooth alignment between back and forward tangents. The back tangent represents the initial grade, while the forward tangent defines the subsequent grade. These curves can be symmetrical, with equal tangent lengths, or nonsymmetrical, with varying lengths. The key points defining a vertical curve include the Point of Vertical Intersection (P.V.I.), where the tangents meet; the Point of...
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Crystal Field Theory - Octahedral Complexes02:58

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Vertical curves are essential in roadway design because they provide smooth transitions between varying roadway grades. Designing vertical curves involves calculating intermediate elevations and identifying the curve's highest or lowest point, which is essential for optimal roadway performance.Intermediate elevations on a vertical curve are determined using the tangent offset method. This method considers the initial elevation at the start of the curve, the grades, and the curve's geometry. The...
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Vertical Alignment of Liquid Crystals Over a Functionalized Flexible Substrate.

B Sivaranjini1, R Mangaiyarkarasi1, V Ganesh2

  • 1Department of Industrial Chemistry, Alagappa University, Karaikudi, 630003, India.

Scientific Reports
|June 13, 2018
PubMed
Summary
This summary is machine-generated.

Researchers developed a new method for aligning liquid crystals (LCs) on flexible plastic substrates. This technique offers a simple, effective, and reusable way to achieve precise vertical alignment for LC displays.

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Area of Science:

  • Materials Science
  • Organic Chemistry
  • Surface Science

Background:

  • Flexible transparent substrates are crucial for advanced display technologies.
  • Achieving controlled liquid crystal (LC) alignment on these surfaces is challenging.
  • Existing alignment methods often lack efficiency or reusability.

Purpose of the Study:

  • To develop a simple and effective method for vertical alignment of liquid crystals on functionalized transparent flexible substrates.
  • To synthesize and characterize a new mesogen for surface modification.
  • To evaluate the alignment capabilities of the modified substrates for different LC phases.

Main Methods:

  • Surface characterization using X-ray photoelectron spectroscopy (XPS) and attenuated total reflection infrared spectroscopy (ATR-IR).
  • Chemical functionalization of cellulose acetate substrate with a synthesized trimethoxysilane-terminated mesogen via silane condensation.
  • Assessment of LC alignment using contact angle (CA) and atomic force microscopy (AFM).

Main Results:

  • Cellulose acetate identified as the main component of the plastic substrate.
  • Successful covalent attachment of the mesogen confirmed by surface analysis techniques.
  • LC-functionalized substrates demonstrated highly efficient homeotropic alignment for both nematic and smectic A phases.
  • Superior alignment ability compared to unmodified and OTS-modified substrates.

Conclusions:

  • The developed method provides an easy, stable, and reusable approach for surface modification of flexible polymer films.
  • The functionalized substrates exhibit excellent homeotropic alignment capabilities for liquid crystals.
  • This technique holds promise for applications requiring precise LC alignment on flexible surfaces.