Shape Engineering of Biomass-Derived Nanoparticles from Hollow Spheres to Bowls through Solvent-Induced Buckling

The realization of asymmetric hollow carbonaceous nanostructures remains a great challenge, especially when biomass is chosen as the carbon resource through hydrothermal carbonization (HTC). Herein, a simple and straightforward solvent-induced buckling strategy is demonstrated for the synthesis of asymmetric spherical and bowl-like carbonaceous nanomaterials. The formation of the bowl-like morphology was attributed to the buckling of the spherical shells induced by the dissolution of the oligomers. The bowl-like particles prepared through this solvent-driven approach demonstrated a well-controlled morphology and a uniform particle size of approximately 360 nm. The obtained nanospheres and nanobowls were loaded with CoS₂ nanoparticles to act as heterogeneous catalysts for the selective hydrogenation of aromatic nitro compounds. As expected, the CoS₂ /nanobowls catalyst showed good tolerance to a wide scope of reducible groups and afforded both high activity and selectivity in almost all the tested substrates.