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On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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Adolf von Baeyer attempted to explain the instabilities of small and large cycloalkane rings using the concept of angle strain — the strain caused by the deviation of bond angles from the ideal 109.5° tetrahedral value for sp3  hybridized carbons. However, while cyclopropane and cyclobutane are strained, as expected from their highly compressed bond angles, cyclopentane is more strained than predicted, and cyclohexane is virtually strain-free. Hence, Baeyer’s theory that...
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Conformable Wearable Electrodes: From Fabrication to Electrophysiological Assessment
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Highly Conformable, Transparent Electrodes for Epidermal Electronics.

Jin-Hoon Kim1, Seung-Rok Kim1, Hye-Jun Kil2

  • 1Department of Materials Science and Engineering , Yonsei University , Seoul 03722 , Korea.

Nano Letters
|June 21, 2018
PubMed
Summary
This summary is machine-generated.

Researchers developed a new transparent electrode for epidermal electronics using adhesive polydimethylsiloxane (PDMS) and silver nanowires (AgNWs). This material offers enhanced conformability and stretchability for wearable sensors like strain and electrocardiogram (ECG) devices.

Keywords:
AgNWsConformabilityECGadhesive electrodesstrain sensor

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Biomedical Engineering

Background:

  • Epidermal electronics require stretchable, transparent, and conformable electrodes.
  • Polydimethylsiloxane (PDMS) is a common substrate, but its mechanical properties need optimization for advanced applications.
  • Silver nanowires (AgNWs) offer conductivity but require robust integration into flexible substrates.

Purpose of the Study:

  • To develop a highly conformable, stretchable, and transparent electrode for epidermal electronics.
  • To enhance the mechanical properties of PDMS for better integration with AgNWs.
  • To fabricate and evaluate wearable strain and electrocardiogram (ECG) sensors using the novel electrode material.

Main Methods:

  • Incorporation of Triton X surfactant into PDMS to create an adhesive PDMS (a-PDMS) matrix.
  • Modulation of PDMS cross-linking by Triton X's interaction with the Pt catalyst.
  • Embedding of AgNWs into the a-PDMS matrix, leveraging polar group interactions.
  • Fabrication of wearable strain and ECG sensors using the AgNW-embedded a-PDMS.

Main Results:

  • Triton X addition significantly improved PDMS adhesion and mechanical compliance.
  • AgNWs were effectively embedded in the a-PDMS matrix, maintaining electrode transparency and conductivity.
  • The resulting AgNW-embedded a-PDMS exhibited enhanced conformability and stretchability.
  • Wearable sensors fabricated with the new material showed improved performance compared to bare PDMS sensors.

Conclusions:

  • The developed AgNW-embedded a-PDMS is a promising material for high-performance epidermal electronics.
  • The surfactant-mediated approach effectively enhances substrate properties for flexible electronic applications.
  • Improved sensor performance highlights the potential of this material for advanced wearable health monitoring.