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Updated: Feb 8, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
Versatile Micropatterns of N-Heterocyclic Carbenes on Gold Surfaces: Increased Thermal and Pattern Stability with
D Thao Nguyen1, Matthias Freitag1, Martin Körsgen2
1Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149, Münster, Germany.
Abstract:
Patterned monolayers of N-heterocyclic carbenes (NHCs) on gold surfaces were obtained by microcontact printing of NHC-CO2 adducts and NHC(H)[HCO3 ] salts. The NHC-modified areas showed an increased conductivity compared to unmodified gold surface areas. Furthermore, the remaining surface areas could be modified with a second, azide-functionalized carbene, facilitating further applications and post-printing modifications. Thorough elucidation by a variety of analytical methods offers comprehensive evidence for the viability of the methodology reported here. The protocol enables facile access to versatile, microstructured NHC-modified gold surfaces with highly stable patterns, enhanced conductivity, and the option for further modification.
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