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Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Complex microtubule structures are present in resting cells and in dividing cells. In resting cells, they are responsible for maintaining the cellular architecture, tracks for intracellular transport, positioning of organelles, assembly of cilia and flagella. They mediate the bipolar spindle assembly for chromosomal segregation and positioning of the cell division plate in dividing cells. The formation of microtubule complex structures depends on the cell type, cell stage, and cell function.
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Structural Properties and Dimensions of Lumber01:21

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Wood's structural properties derive from fibers aligned along the tree's length, contributing significantly to its mechanical strength. Wood exhibits up to twenty times greater tensile strength along these fibers compared to across them, and generally shows better performance under compression than tension. The length of fibers varies, with hardwoods having fibers around one twenty-fifth inch long and softwoods ranging from one-eighth to one-third inch.
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Structure and Physical Properties of Alkynes02:37

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Introduction:
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Updated: Feb 8, 2026

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets
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Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets

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Sterically Crowded Trianglimines-Synthesis, Structure, Solid-State Self-Assembly, and Unexpected Chiroptical

Natalia Prusinowska1,2, Mateusz Bardziński1, Agnieszka Janiak1

  • 1Department of Chemistry, Adam Mickiewicz University, Umultowska 89B, 61 614, Poznan, Poland.

Chemistry, an Asian Journal
|June 29, 2018
PubMed
Summary

Chiral trianglimine macrocycles with bulky substituents were synthesized. These molecules exhibit unique self-assembly behaviors and unexpectedly high exciton Cotton effects in electronic circular dichroism spectra.

Keywords:
circular dichroismexciton couplingiminemacrocyclesself-assembly

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Area of Science:

  • Supramolecular Chemistry
  • Organic Synthesis
  • Spectroscopy

Background:

  • Chiral macrocycles are important in molecular recognition and asymmetric catalysis.
  • Trianglimines are a class of macrocycles known for their unique structures and stability.
  • The influence of bulky substituents on macrocyclic conformation and electronic properties requires further investigation.

Purpose of the Study:

  • To synthesize novel chiral, triangular-shape hexaimine macrocycles (trianglimines) with bulky alkynyl or aryl substituents.
  • To investigate the self-assembly behavior and conformational preferences of these trianglimines.
  • To explore the impact of substituents on the electronic properties and circular dichroism spectra.

Main Methods:

  • Synthesis of trianglimine macrocycles via macrocyclization reactions.
  • Characterization using experimental techniques (e.g., crystallography, spectroscopy).
  • Theoretical studies, including Density Functional Theory (DFT) optimization.

Main Results:

  • High yields of trianglimine macrocycles were achieved due to the inherent stability of the ring.
  • Substituents induced anti conformations in aromatic linkers, leading to bowl-like or pillararene-like structures.
  • Unexpectedly high exciton Cotton effects were observed in electronic circular dichroism (ECD) spectra, indicating significant chiroptical properties.

Conclusions:

  • The stability of the trianglimine core facilitates high-yield synthesis.
  • Bulky substituents dictate macrocycle conformation and self-assembly into dimers or pillararene-like structures.
  • The observed strong exciton Cotton effects highlight the sensitivity of electronic properties to structural modifications and substituent effects.