Improvement in the photoelectric conversion efficiency for the flexible fibrous dye-sensitized solar cells

A dye-sensitized and flexible TiO₂ fiber with multilayer structure was prepared by using brush method as the photoanode in the efficient flexible fibrous dye-sensitized solar cells (FFDSSCs) to avoid electronic recombination and improve the electronic capture efficiency. The composite Pt counter electrode, preparation from the surface modification of the electrodeposited Pt wire by using a simple one-step thermal decomposition approach of H₂PtCl₆ isopropanol and n-butyl alcohol (volume ratio = 1:1) solution, provided a significant improvement in electrocatalytic activity, which was confirmed by extensive electrochemical tests. The FFDSSC assembled with the fiber-shaped TiO₂ photoanode and the composite Pt counter electrode achieves an enhanced photoelectric conversion efficiency of 6.35%, higher than that of the FFDSSC with monolayer fibrous TiO₂ photoanode and electrodeposited Pt wire counter electrode. More importantly, the photoelectric conversion efficiency of 6.35% is comparable to that of the FFDSSC based on the pure Pt wire counter electrode (6.32%). The FFDSSC with high elasticity, flexibility, and stretchability can adapt to complex mechanical deformations, which is of great significance for the development of wearable electronics in the future.