A dual pH-responsive supramolecular gelator with aggregation-induced emission properties
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Updated: Feb 8, 2026

Synthesis and Characterization of Supramolecular Colloids
Published on: April 22, 2016
Marlen Externbrink1, Steffen Riebe, Carsten Schmuck
1Institute of Organic Chemistry, University of Duisburg-Essen, Universitätsstrasse 7, 45117 Essen, Germany. jens.voskuhl@uni-due.de carsten.schmuck@uni-due.de.
Abstract:
Functionalising AIE-active aromatic thioethers with self-complementary zwitterionic binding sites leads to a dual pH-responsive supramolecular organogelator with aggregation-induced emission (AIE) properties. The self-assembled fibrillar gel network is highly fluorescent (λem = 490 nm), whereas the addition of both acid and base leads to the sol state with a loss of emission. More over, the gel was found to be thermo- and mechanoresponsive.
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