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Updated: Feb 8, 2026

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Dynamic Electrochemical Measurement of Chloride Ions
Published on: February 5, 2016
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Carbenium ion formation by fragmentation of electrochemically generated oxonium ions
Anna Lielpetere1, Aigars Jirgensons
1Latvian Institute of Organic Synthesis, Aizkraukles 21, Riga, LV-1006, Latvia. aigars@osi.lv.
Organic & Biomolecular Chemistry
|July 5, 2018
Abstract:
Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.
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