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Diffusion01:12

Diffusion

220.2K
Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
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Diffusion01:21

Diffusion

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Diffusion is a type of passive transport. In passive transport, a substance tends to move from an area of high concentration to an area of low concentration until the concentration is equal across the space. For example, take the diffusion of substances through the air. When someone opens a perfume bottle in a room filled with people, the perfume is at its highest concentration in the bottle and is at its lowest at the edges of the room. The perfume vapor will diffuse, or spread away, from the...
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Standard Electrode Potentials03:02

Standard Electrode Potentials

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On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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Drugs Affecting GI Tract Motility: Adsorbents as Antidiarrheal Agents01:20

Drugs Affecting GI Tract Motility: Adsorbents as Antidiarrheal Agents

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Diarrhea is characterized by the occurrence of frequent, watery bowel movements. Various factors can trigger diarrhea, including viral or bacterial infections, foodborne illnesses, side effects from certain medications, and underlying digestive disorders. If not adequately managed, diarrhea can lead to complications such as dehydration, electrolyte imbalances, and nutrient deficiencies. Severe diarrhea can lead to significant weight loss, malnutrition, and weakened immune function.
Adsorbents...
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Facilitated Diffusion01:16

Facilitated Diffusion

1.3K
The plasma membrane, a critical structure in cellular biology, houses an array of transporters, or carrier proteins, interspersed within its lipid bilayer. These proteins play a crucial role in solute transport through facilitated diffusion, a form of passive diffusion that uses transporters to move the molecules across the membrane.
In this process, substrates such as organic compounds and ions interact with a transporter on one side, triggering conformational changes in proteins that enable...
1.3K
Electrodes: Overview01:17

Electrodes: Overview

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 Electrochemical measurements are conducted in an electrochemical cell composed of various components that control and measure the current and potential. One fundamental component is electrodes, conductive materials that enable electron transfer reactions at their surfaces.
There are two main types of electrodes in electrochemical cells. The first type, known as the working or indicator electrode, has a potential that is sensitive to the analyte's concentration and reacts to changes in...
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Related Experiment Video

Updated: Feb 8, 2026

Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography
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Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography

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Formation and Diffusion of Subsurface Adsorbates at Electrodes.

Björn Rahn1, Olaf M Magnussen1

  • 1Institute of Experimental and Applied Physics , Kiel University , Olshausenstrasse 40 , 24098 Kiel , Germany.

Journal of the American Chemical Society
|July 10, 2018
PubMed
Summary
This summary is machine-generated.

Researchers observed a subsurface species forming at metal electrodes and migrating within the surface layer. This discovery, using scanning tunneling microscopy, reveals enhanced surface diffusion via vacancy-mediated pathways, potentially impacting electrocatalysis.

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Area of Science:

  • Surface Science
  • Electrochemistry
  • Materials Science

Background:

  • Understanding interfacial processes at metal electrodes is crucial for electrocatalysis.
  • The dynamics of species within the surface layer of electrodes are not fully understood.
  • Electrochemical double layers influence surface reactions.

Purpose of the Study:

  • To directly observe the formation and migration of subsurface species at metal electrodes.
  • To investigate the role of surface vacancies in species diffusion.
  • To explore the implications of enhanced surface dynamics for electrocatalytic reactions.

Main Methods:

  • In situ video-rate scanning tunneling microscopy (STM).
  • Studied adsorbed sulfide on bromide-covered Ag(100) electrodes in liquid electrolytes.
  • Analyzed reversible transitions between surface adsorption sites and subsurface vacancies.

Main Results:

  • Direct observation of a subsurface species formation and migration below the electrochemical double layer.
  • Identified reversible transitions of adsorbed sulfide between surface sites and first-layer Ag vacancies.
  • Observed orders of magnitude enhancement in sulfide surface diffusion attributed to vacancy-mediated pathways.

Conclusions:

  • Subsurface species formation and migration are dynamic processes occurring at metal electrode surfaces.
  • Vacancy-mediated diffusion significantly enhances surface species mobility.
  • These findings suggest new pathways for electrocatalytic reactions and material growth processes.