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Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

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Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
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Kinetic Molecular Theory and Gas Laws Explain Properties of Gas Molecules02:34

Kinetic Molecular Theory and Gas Laws Explain Properties of Gas Molecules

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The test of the kinetic molecular theory (KMT) and its postulates is its ability to explain and describe the behavior of a gas. The various gas laws (Boyle’s, Charles’s, Gay-Lussac’s, Avogadro’s, and Dalton’s laws) can be derived from the assumptions of the KMT, which have led chemists to believe that the assumptions of the theory accurately represent the properties of gas molecules.
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Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion03:48

Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion

31.4K
Although gaseous molecules travel at tremendous speeds (hundreds of meters per second), they collide with other gaseous molecules and travel in many different directions before reaching the desired target. At room temperature, a gaseous molecule will experience billions of collisions per second. The mean free path is the average distance a molecule travels between collisions. The mean free path increases with decreasing pressure; in general, the mean free path for a gaseous molecule will be...
31.4K
Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Related Experiment Video

Updated: Feb 8, 2026

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
09:05

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials

Published on: May 15, 2015

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Two Consecutive Magneto-Structural Gas-Solid Transformations in Non-Porous Molecular Materials.

Julia Miguel-Donet1, Javier López-Cabrelles1, Néstor Calvo Galve1

  • 1Instituto de Ciencia Molecular (ICMol), Universitat de València, c/ Catedrático José Beltrán 2, 46980, Paterna, Spain.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|July 11, 2018
PubMed
Summary

This study introduces a non-porous coordination polymer that changes its magnetic properties and structure when exposed to and releasing hydrogen chloride (HCl) gas. This reversible magnetostructural transformation offers potential for novel switches and sensors.

Keywords:
coordination polymersmagnetismnon-porous materialssolid-gas reactionssolid-state materials

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Spectral and Angle-Resolved Magneto-Optical Characterization of Photonic Nanostructures
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Area of Science:

  • Solid-state chemistry
  • Magnetism
  • Coordination polymers

Background:

  • External stimuli can modify solid-state material properties, enabling applications like switches and sensors.
  • Gas sorption studies in coordination polymers typically involve porous materials, not non-porous ones.
  • Reversible changes in material properties are crucial for developing responsive devices.

Purpose of the Study:

  • To investigate a 1D non-porous coordination polymer's response to hydrogen chloride (HCl) gas.
  • To explore the magnetostructural transformations induced by gas incorporation and release.
  • To demonstrate the potential of this material for switch and sensor applications.

Main Methods:

  • Synthesis of a 1D non-porous coordination polymer.
  • Exposure of the polymer to hydrogen chloride (HCl) gas.
  • X-ray single-crystal diffraction to analyze structural changes.
  • Magnetic property measurements to track magnetic behavior modifications.

Main Results:

  • The coordination polymer incorporates HCl gas, leading to atomic rearrangement and altered magnetic behavior.
  • Extrusion of HCl gas induces a second structural rearrangement and modifies magnetic pathways.
  • A two-step, reversible magnetostructural transformation was confirmed via X-ray single-crystal diffraction.

Conclusions:

  • A non-porous coordination polymer exhibits reversible, stimulus-responsive magnetostructural transformations upon interaction with HCl gas.
  • The observed changes highlight the potential for designing novel solid-state switches and sensors based on coordination polymers.
  • This work expands the understanding of gas-solid interactions in non-porous coordination systems.