Chitosan-templated Pt nanocatalyst loaded mesoporous SnO₂ nanofibers: a superior chemiresistor toward acetone...

In this work, we introduce a chitosan-Pt complex (CS-Pt) as an effective template for catalytic Pt sensitization and creation of abundant mesopores in SnO2 nanofibers (NFs). The Pt particles encapsulated by the CS exhibit ultrasmall size (∼2.6 nm) and high dispersion characteristics due to repulsion between CS molecules. By combining CS-Pt with electrospinning, mesoporous SnO2 NFs uniformly functionalized with the Pt catalyst (CS-Pt@SnO2 NFs) are synthesized. Particularly, numerous mesopores with diameters of ∼20 nm form through the decomposition of CS, while a small SnO2 grain size (14.32 nm) is achieved by the pinning effect of CS. It is observed that CS-Pt@SnO2 NFs exhibit outstanding response (Rair/Rgas = 141.92 at 5 ppm), excellent selectivity, stability, and fast response (12 s)/recovery (44 s) speed toward 1 ppm of acetone at 350 °C and high humidity (90% RH). In addition, by applying an exponential fitting tool to experimental response values toward 0.1-5 ppm of acetone, it is estimated that CS-Pt@SnO2 NFs can detect 5 ppb of acetone with a notable response (Rair/Rgas = 2.9). Furthermore, the sensor array based on CS-Pt@SnO2 NFs, CS-driven SnO2 NFs, polyol-Pt loaded SnO2 NFs, and dense SnO2 NFs obviously classifies simulated diabetic breath and healthy human breath by using a pattern recognition tool. These results clearly demonstrate that mesoporous SnO2 NFs, particularly functionalized with CS-Pt templated nanocatalysts, open up a new class of sensing layers offering high sensitivity and selectivity.