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Norbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs)
Jordan R Engstrom1, Aramballi J Savyasachi2, Marzieh Parhizkar3
1School of Life and Environmental Sciences , Deakin University , Waurn Ponds , Victoria 3216 , Australia .
Abstract:
Phenylalanine functionalised norbornene (9:Na) functions as a potent, low molecular-mass (MW = 333 Da) ionic organogelator with a minimum gelating concentration of 0.5 wt% in THF, i-PrOH, 1,4-dioxane and n-BuOH. Fibrous crystals form in the gel and X-ray crystallography identified a cation mediated helical assembly process controlled by the chirality of the phenylalanine. In addition to excellent gelating properties 9:Na readily forms aqueous biphasic and triphasic systems.
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