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Updated: Feb 7, 2026

Bridging the Bio-Electronic Interface with Biofabrication
Published on: June 6, 2012
Phenylene-bridged cross-conjugated 1,2,3-trisilacyclopentadienes
Hui Zhao1, Lukas Klemmer, Michael J Cowley
1Krupp-Chair of General and Inorganic Chemistry, Saarland University, 66123, Saarbrücken, Germany. scheschkewitz@mx.uni-saarland.de.
Abstract:
1,2,3-Trisilacyclopentadienes are obtained from the reactions of cyclotrisilene c-Si3R4 (R = iPr3C6H2) with phenyl and diphenyl acetylene, respectively. With 1,4-diethynyl benzene the cross-conjugated bridging of two of the Si3C2 cycles by a para-phenylene linker is achieved. UV/vis spectroscopy indicates a small but significant effect of cross-conjugation, which is confirmed by TD-DFT calculations. The formation mechanism of the 1,2,3-trisilacyclopentadienes is elucidated by VT NMR.
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