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Sustained production of H2O2 in alkaline water solution using borate and phosphate-modified Au/TiO2 photocatalysts
Xianqiang Xiong1, Xiao Zhang, Shengwei Liu
1State Key Laboratory of Silicon Materials and Department of Chemistry, Zhejiang University, Hangzhou 310027, China. xuym@zju.edu.cn.
Abstract:
UV irradiation of Au/TiO2 photocatalysts in the presence of borate and phosphate anions can produce H2O2 at a millimolar level in alkaline water solution. The positive effect of the anions is ascribed to the anion-mediated hole transfer from Au/TiO2 to an electron donor which thus accelerates the two-electron reduction of O2 to H2O2.
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