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Strong-Field Fourier Transform Vibrational Spectroscopy of D_{2}^{+} Using Few-Cycle Near-Infrared Laser Pulses
Toshiaki Ando1, Atsushi Iwasaki1, Kaoru Yamanouchi1
1Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Abstract:
The photoionization of D_{2} and dissociation of the resultant D_{2}^{+} are monitored by pump-probe measurements using intense near-infrared few-cycle laser pulses. The yields of D_{2}^{+} and D^{+} recorded up to the pump-probe delay time of 527 ps exhibit oscillatory structures reflecting the motion of the created vibrational wave packet of D_{2}^{+}, and the Fourier transform of the data in time domain reveals the vibrational level separations with uncertainties of 0.0002-0.0097 cm^{-1}, showing a potential application of the strong-field pump-probe measurements to high-resolution spectroscopy of molecular ions.
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