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Analysis and Specification of Starch Granule Size Distributions
Published on: March 4, 2021
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Optimizing electric corona treatment for hydroxypropylated starch-based coatings.
Johanna Lyytikäinen1, Sami-Seppo Ovaska1, Ekaterina Soboleva2
1Lappeenranta University of Technology, LUT Energy Systems, Packaging Technology, P.O. Box 20, FI-53851 Lappeenranta, Finland.
Carbohydrate Polymers
|July 16, 2018
Summary
Plasma corona treatments effectively modify bio-based coatings by altering surface properties. This research optimizes electric discharge for enhanced barrier coatings using starch binders without damaging the material.
Area of Science:
- Materials Science
- Surface Chemistry
- Polymer Science
Background:
- Bio-based dispersion barrier coatings are crucial for sustainable packaging.
- Replacing fossil-based binders with bio-based alternatives like starch is an ongoing challenge.
- Optimizing surface modification techniques is essential for enhancing coating performance.
Purpose of the Study:
- To investigate the effects of direct current and alternating current (plasma) corona treatments on bio-based dispersion barrier coatings.
- To evaluate the suitability of starch as a thermoplastic bio-based binder in these coatings.
- To understand and optimize corona discharge parameters for effective surface modification without substrate damage.
Main Methods:
- Utilized a novel laboratory-scale sheet-fed device for corona treatments.
- Employed Atomic Force Microscopy (AFM) for topographical analysis.
- Conducted X-ray Photoelectron Spectroscopy (XPS), contact angle, and surface energy measurements for chemical and surface property evaluation.
Main Results:
- Corona treatments (both DC and AC plasma) induced significant topographical, mechanical, and chemical surface changes.
- Surface topography became smoother, indicating nanoparticle migration and re-orientation.
- XPS confirmed partial starch decomposition and revealed changes in surface chemistry.
- Contact angle and surface energy measurements demonstrated altered surface properties.
Conclusions:
- Plasma corona treatments are effective in modifying bio-based dispersion barrier coatings with starch binders.
- Optimized corona discharge can enhance surface properties while minimizing substrate damage.
- Further research is needed to fully understand and mitigate reverse side effects and strike-through phenomena.
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