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Published on: December 4, 2014
Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon: An Unusual Approach
Paulina A Kobielska1, Richard Telford1, Jemma Rowlandson2
1School of Chemistry and Biosciences , University of Bradford , Richmond Road , Bradford BD7 1DP , United Kingdom.
Abstract:
A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g-1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.
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