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Pt Nanoparticles Supported on Nitrogen-Doped-Carbon-Decorated CeO2 for Base-Free Aerobic Oxidation of
Changxuan Ke1, Mengyuan Li1, Guoli Fan1
1State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, P. O. BOX 98, Beijing, 100029, P. R. China.
Abstract:
Currently, the base-free aerobic oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to produce 2,5-furandicarboxylic acid (FDCA) is attracting intense interest due to its prospects for the green, sustainable, and promising production of biomass-based aromatic polymers. Herein, we have developed a new Pt catalyst supported on nitrogen-doped-carbon-decorated CeO2 (NC-CeO2 ) for the aerobic oxidation of HMF in water without the addition of any homogeneous base. It was demonstrated that the small-sized Pt particles could be well dispersed on the surface of the hybrid NC-CeO2 support, and the activity of the supported Pt catalyst depended strongly on the surface structure and properties of the catalysts. The as-fabricated Pt/NC-CeO2 catalyst, with abundant surface defects, enhanced basicity, and favorable electron-deficient metallic Pt species, enabled an almost 100 % yield of FDCA in water with molecular oxygen (0.4 MPa) at 110 °C for 8 h without the addition of any homogeneous base, which is indicative of exceptional catalytic performance. Furthermore, this Pt/NC-CeO2 catalyst also showed good stability and reusability owing to strong metal-support interactions. An understanding of the role of surface structural defects and basicity of the hybrid NC-CeO2 support provides a basis for the rational design of high-performance and stable supported metal catalysts with practical applications in various transformations of biomass-derived compounds.
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