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Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors
Hui Chen1, Feng Yu1, Gang Wang1
1Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, P. R. China.
Abstract:
N,S-Doped activated carbon was directly prepared via a facile and cost-efficient hydrothermal reaction, followed by alkali activation of elm flower (EL)-derived biomass. The EL-derived activated carbon (ELAC) had N and S contents of 2.21 and 6.06 atom %, respectively, in addition to a high Brunauer-Emmett-Teller (BET) surface area of 2048.6 m2 g-1 and moderate pore volume of 0.88 cm3 g-1. Owing to its high BET surface area and N/S functional groups, ELAC achieved a specific capacitance of 275 F g-1 at a current density of 1 A g-1 and retained a capacitance of 216 F g-1 at 20 A g-1. In addition, a symmetric supercapacitor based on N,S-self-doped ELAC electrode provided a capacitance of 62 F g-1 at a current density of 10 A g-1, with maximum energy and power densities of 16.8 Wh kg-1 and 600 W kg-1, respectively. The capacitance retention was also high, at 87.2%, at 4 A g-1 after 5000 cycles.
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