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Probing the structure-property-composition relationship in organic-inorganic tri-halide perovskites
Julia L Payne1, Chengsheng Ni, Jonathon R Harwell
1School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK. jlp8@st-andrews.ac.uk jtsi@st-andrews.ac.uk.
Abstract:
Here, we have synthesised a range of samples, with the formula (CH3NH3)1-2x(H3NC2H4NH3)xPbI3, with different levels of ethylenediammonium substitution to probe non-stoichiometry at the A-site of the perovskite. A single phase region was identified and is accompanied by a change in photophysical properties. The influence of aliovalent substitution with ethylenediammonium results in a decrease in HOMO level from -5.31 eV for x = 0 to -5.88 eV for x = 0.15.
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