Evaluation of phosphate adsorption on zirconium/magnesium-modified bentonite

In this work, a zirconium/magnesium-modified bentonite (ZrMgBT) was prepared and characterized by SEM, EDS, XRD and pH_PZC. The performance and mechanism of phosphate adsorption onto ZrMgBT was evaluated in detail using batch experiments and ³¹P NMR. Results showed the adsorption isotherm data were well described by the Langmuir, Freundlich and Dubinin-Radushkevich models, and the kinetic data fitted better to the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The phosphate adsorption capacity of ZrMgBT was slightly affected by the presence of Na⁺, K⁺, Cl^-, [Formula: see text] and [Formula: see text], but it was enhanced by coexisting Mg²⁺ and [Formula: see text]. The mechanism for phosphate adsorption onto ZrMgBT at pH 7 was mainly the complexation reaction between phosphate and zirconium. In addition, ZrMgBT exhibited more excellent adherence to phosphate than zirconium-modified bentonite (ZrBT). Especially, the maximum monolayer phosphate adsorption capacity for ZrMgBT at pH 7 and 0.5 g/L of adsorbent dosage calculated based on the Langmuir isotherm model (13.0 mg P/g) was 67.5% higher than that for ZrBT. The higher phosphate adsorption capacity for ZrMgBT than ZrBT could be attributed to the higher specific surface area as well as higher Mg²⁺ releasing ability of the former. The enhancement of phosphate adsorption by the release of Mg²⁺ from ZrMgBT could be mainly due to the formation of [Formula: see text] in the solution firstly and then the adsorption of [Formula: see text] on ZrMgBT forming ≡Zr(OPO₃H)Mg on the ZrMgBT surface. In general, we conclude that ZrMgBT is a more promising adsorbent for phosphate removal from aqueous solution than ZrBT.