The traffic signature on the vertical PM profile: Environmental and health risks within an urban roadside environment

In an attempt to investigate the traffic-impacted vertical aerosols profile and its relationship with potential carcinogenicity and/or mutagenicity, samples of different sized airborne particles were collected in parallel at the 1st and 5th floor of a 19 m high building located next to one of the busiest roads of Athens. The maximum daily concentrations were 65.9, 42.5 and 38.5 μg/m³, for PM₁₀, PM_2.5 and PM₁, respectively. The vertical concentration ratio decreased with increasing height verifying the role of the characteristics of the area (1st/5th floor: 1.21, 1.13, 1.09 for PM₁₀, PM_2.5 and PM₁, respectively). Chemically, strengthening the previous hypothesis, the collected particles were mainly carbonaceous (68%-93%) with the maximum budget of the polyaromatic hydrocarbons being recorded near the surface (1st/5th floor: 1.84, 1.07, 1.15 for PM₁₀, PM_2.5 and PM₁, respectively). The detected PM-bound PAHs along with the elements as well as the carbonaceous and ionic constituents were used in a source apportionment study. Exhaust and non-exhaust emissions, a mixed source of biomass burning and high temperature combustion processes (natural gas, gasoline/diesel engines), sea salt, secondary and soil particles were identified as the major contributing sources to the PM pollution of the investigated area. With respect to the health hazards, the calculation of the Benzo[a]Pyrene toxicity equivalency factors underlined the importance of the height of residence in buildings for the level of the exposure (1st/5th floor: B[a]P_TEQ: 1.82, 1.12, 1.10, B[a]P_MEQ: 1.85, 1.13, 1.09 for PM₁₀, PM_2.5 and PM₁, respectively). Finally, despite its verified significance as a surrogate compound for the mixture of the hydrocarbons (its contribution up to 72%, 79% on the level of the 1st and 5th floor, respectively), the importance of the incorporation of PAH species in addition to B[a]P when assessing PAH toxicity was clearly documented.