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Related Concept Videos

Alkali Metals03:06

Alkali Metals

24.8K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.8K
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.4K
Properties of Transition Metals02:58

Properties of Transition Metals

29.9K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
29.9K
Protein-protein Interfaces02:04

Protein-protein Interfaces

14.7K
Many proteins form complexes to carry out their functions, making protein-protein interactions (PPIs) essential for an organism's survival. Most PPIs are stabilized by numerous weak noncovalent chemical forces. The physical shape of the interfaces determines the way two proteins interact. Many globular proteins have closely-matching shapes on their surfaces, which form a large number of weak bonds. Additionally, many PPIs occur between two helices or between a surface cleft and a...
14.7K
Protein-Protein Interfaces02:04

Protein-Protein Interfaces

4.5K
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Bonding in Metals02:32

Bonding in Metals

52.5K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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Engineering stable interfaces for three-dimensional lithium metal anodes.

Jin Xie1, Jiangyan Wang1, Hye Ryoung Lee1

  • 1Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA.

Science Advances
|August 1, 2018
PubMed
Summary
This summary is machine-generated.

Researchers developed a novel method to stabilize lithium metal anodes for advanced batteries. A thin coating on a hollow carbon host prevents parasitic reactions, enabling over 500 cycles with high efficiency.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Lithium metal anodes are promising for high-energy-density batteries (Li-S, Li-O2) but face challenges with cyclability and safety.
  • Parasitic reactions between lithium metal and liquid electrolytes form unstable solid electrolyte interphases, degrading performance.

Purpose of the Study:

  • To develop a method to prevent parasitic reactions in lithium metal anodes.
  • To improve the cycling stability and safety of lithium metal anodes for advanced battery applications.

Main Methods:

  • Utilized atomic layer deposition to apply a thin-layer coating on a hollow carbon host.
  • Engineered the coating to guide lithium deposition within the hollow carbon spheres and seal surface imperfections.

Main Results:

  • The coated hollow carbon host successfully encapsulated lithium metal, preventing electrolyte infiltration and parasitic reactions.
  • Achieved over 500 cycles with 99% coulombic efficiency in an ether-based electrolyte at 0.5 mA/cm2 and 1 mAh/cm2 cycling capacity.
  • Demonstrated significantly improved cycling behavior and stability compared to conventional lithium metal anodes.

Conclusions:

  • Encapsulating lithium metal within a coated hollow carbon host effectively suppresses parasitic reactions.
  • This approach offers a viable strategy for developing stable and high-performance lithium metal anodes for next-generation batteries.