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Hierarchically ordered structures of disk-cube triads containing hexa-peri-hexabenzocoronene and polyhedral
Wei Zhang1, Kehua Gu, Pingping Hou
1Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, and College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. zshen@pku.edu.cn fanxh@pku.edu.cn.
Abstract:
Obtaining nanoscale-ordered structures is important for the development of nanotechnology. We designed and synthesized a series of disk-cube triads containing one hexa-peri-hexabenzocoronene (HBC) and two polyhedral oligomeric silsesquioxane (POSS) moieties, HBC-2POSS. The two POSS units were linked via ester or amide bonds. With the amide linkage used, the hydrogen bonding that was introduced affected the balance between the π-π interaction of HBC cores and crystallization interaction of POSS units. Hierarchically ordered structures were obtained from HBC-2POSS triads owing to the synergistic effect of multiple secondary interactions: π-π interaction, hydrogen bonding, and crystallization interaction. As organic-inorganic hybrid materials, these HBC-2POSS triads are promising candidates for templates <10 nm.
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