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Published on: November 5, 2015
Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor
Ming Li1, Chuang Ma1, Xiong Liu2
1Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials , Key Laboratory for the Synthesis and Application of Organic Functional Molecules , Ministry of Education , Hubei Key Laboratory of Polymer Materials , College of Chemistry and Chemical Engineering , Hubei University , Wuhan 430062 , People's Republic of China .
Abstract:
Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar-layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P4). Our research may provide a new approach for the synthesis of various 2D materials.
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