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The silicon cycle impacted by past ice sheets.

Jon R Hawkings1, Jade E Hatton2, Katharine R Hendry3

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Glacier meltwater runoff significantly lowers river silicon isotope (δ³⁰Si) values. This finding helps explain ocean silicon changes and suggests a link between ice sheets, ocean silicon, and atmospheric CO₂.

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Area of Science:

  • Geochemistry
  • Paleoclimatology
  • Oceanography

Background:

  • Global riverine silicon (Si) concentrations and isotope composition (δ³⁰Si) are influenced by glacial-interglacial cycles.
  • Understanding these changes is crucial for reconstructing past climate and ocean conditions.

Purpose of the Study:

  • To investigate the impact of ice sheet dynamics on riverine silicon isotope composition.
  • To quantify the contribution of glacial meltwater to ocean δ³⁰Si changes.
  • To explore potential feedbacks between ice sheets, ocean Si, and atmospheric CO₂.

Main Methods:

  • Analysis of δ³⁰Si composition in meltwater runoff from a Greenland Ice Sheet catchment.
  • Comparison of glacial runoff δ³⁰Si with non-glacial rivers.
  • Examination of marine sediment cores near Iceland for evidence of meltwater pulses.

Main Results:

  • Glacial meltwater runoff exhibits the lightest δ³⁰Si values (-0.25 ± 0.12‰) recorded in running waters.
  • The decline in glacial runoff since the Last Glacial Maximum (LGM) may account for 0.06–0.17‰ of the observed ocean δ³⁰Si rise (0.5–1.0‰).
  • Marine sediment cores indicate transient, low-δ³⁰Si meltwater pulses during glacial termination.

Conclusions:

  • Ice sheet dynamics significantly influence riverine silicon isotope signatures.
  • Reduced glacial runoff during interglacial periods contributes to rising ocean δ³⁰Si.
  • A potential feedback loop exists between ice sheet expansion, ocean Si export, and atmospheric CO₂ via diatom activity.