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Weak Base Solutions03:21

Weak Base Solutions

25.3K
Some compounds produce hydroxide ions when dissolved by chemically reacting with water molecules. In all cases, these compounds react only partially and so are classified as weak bases. These types of compounds are also abundant in nature and important commodities in various technologies. For example, global production of the weak base ammonia is typically well over 100 metric tons annually, being widely used as an agricultural fertilizer, a raw material for chemical synthesis of other...
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Weak Acid Solutions04:02

Weak Acid Solutions

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Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
43.2K
Refrigerators and Heat Pumps01:07

Refrigerators and Heat Pumps

3.0K
Refrigerators or heat pumps are heat engines operating in a reverse direction. For a refrigerator, the focus is on removing heat from a specific area, whereas, for a heat pump, the focus is on dumping heat into one particular area. A refrigerator (or heat pump) absorbs heat Qc from the cold reservoir at Kelvin temperature Tc and discards heat Qh to the hot reservoir at Kelvin temperature Th, while work W is done on the engine’s working substance.
A household refrigerator removes heat from...
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Titration of a Weak Acid with a Weak Base01:08

Titration of a Weak Acid with a Weak Base

4.9K
Weak acids and bases do not undergo dissociation completely, and titrations between these two are rarely studied. When such studies are performed, say, for the titration of a weak acid with a weak base, the titration curve plots the change in pH as a function of the volume of base added. Take the titration of acetic acid with ammonia, for instance. During the titration, these two species form ammonium acetate and water, but the pH change is slow and gradual.
As a result, there is no simple...
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Titration Calculations: Weak Acid - Strong Base03:55

Titration Calculations: Weak Acid - Strong Base

49.3K
Calculating pH for Titration Solutions: Weak Acid/Strong Base
For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be represented as:
49.3K
Internal Energy02:00

Internal Energy

36.8K
The total of all possible kinds of energy present in a substance is called the internal energy (U), sometimes symbolized as E. Suppose a system with initial internal energy, Uinitial, undergoes a change in energy (transfer of work or heat), and the final internal energy of the system is Ufinal. Change in internal energy equals the difference between Ufinal and Uinitial.
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Related Experiment Video

Updated: Feb 6, 2026

Detection of Ligand-activated G Protein-coupled Receptor Internalization by Confocal Microscopy
10:24

Detection of Ligand-activated G Protein-coupled Receptor Internalization by Confocal Microscopy

Published on: April 9, 2017

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Refrigeration beyond weak internal coupling.

Stella Seah1, Stefan Nimmrichter2, Valerio Scarani1,2

  • 1Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542, Singapore.

Physical Review. E
|August 17, 2018
PubMed
Summary
This summary is machine-generated.

This study reveals optimal quantum absorption refrigeration occurs at moderate spin coupling strengths. Stronger coupling introduces new heat channels and invalidates common approximations, hindering cooling performance.

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Area of Science:

  • Quantum thermodynamics
  • Open quantum systems
  • Quantum refrigeration

Background:

  • Quantum absorption refrigerators utilize quantum systems for cooling.
  • Previous models approximated performance in weak or ultrastrong coupling regimes.
  • The transition between these regimes and optimal performance conditions remained unclear.

Purpose of the Study:

  • To develop a unified open quantum system model for a three-spin quantum absorption refrigerator.
  • To accurately describe performance across all interspin coupling strengths.
  • To identify conditions for optimal refrigeration and understand limitations.

Main Methods:

  • Utilized a refined open quantum system model.
  • Analyzed the transition between weak and ultrastrong coupling limits.
  • Investigated the impact of interspin coupling on energy exchange and thermal bath interactions.

Main Results:

  • The model bridges previous approximations, predicting optimal cooling at moderate coupling strengths.
  • Deviations from the rotating wave approximation and new heat channels impede cooling.
  • High-temperature work reservoirs can hinder refrigeration in the strong coupling regime.

Conclusions:

  • A unified model provides a more accurate description of quantum absorption refrigerators.
  • Optimal performance is sensitive to interspin coupling strength and reservoir properties.
  • Understanding these factors is crucial for designing efficient quantum cooling devices.