Marigold Flower-Like Assemblies of Phosphorescent Iridium-Silver Coordination Polymers

Racemic and enantiopure phosphorescent iridium(III)-silver(I) coordination polymers are reported. The polymers rac-, Λ-, and Δ-IrAg were formed, respectively, by the assembly of the chiral iridium metalloligands rac-, Λ-, and Δ-[Ir(mesppy)₂ (qpy)]PF₆ (rac-, Λ- and Δ-Ir) where mesppy is 2-phenyl-4-mesitylpyridinato and qpy is 4,4':2',2'':4'',4'''-quaterpyridine, and Ag⁺ ions through N_py -Ag linear coordination. The polymers have been characterized in MeNO₂ solution by ¹ H and ¹ H DOSY NMR and CD spectroscopies and in the solid-state by scanning electron microscopy (SEM). The crystal structures of the racemic polymer rac-IrAg has been obtained by X-ray diffraction. The polymers rac-, Λ-, and Δ-IrAg exhibited orange/red emission in solution, in films and as crystals, with intensities comparable to those of the corresponding iridium metalloligands rac-, Λ-, and Δ-Ir. The morphology of the enantiopure polymers in the solid-state resembles marigold flower-like nano-porous assemblies while the racemic polymer possesses an irregular morphology formation.