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Published on: February 7, 2017
A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO2
Melis S Duyar1,2, Charlie Tsai1,2, Jonathan L Snider1,2
1SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
Abstract:
Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2 /H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2 . We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2 /H2 feeds.
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