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Polymers02:34

Polymers

41.0K
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Polymers02:34

Polymers

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Shear Diagram01:27

Shear Diagram

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In the study of beam mechanics, shear diagrams play a crucial role in understanding the distribution of shear forces along the length of a beam. Consider a beam AB that is supported at both ends and subjected to perpendicular loads.
First, a free-body diagram of the beam is drawn, representing all the external forces and internal reactions acting on the beam. One can calculate the reaction forces at each support by employing the equilibrium equations of force and moment. The vertical component...
1.7K
Shearing Stress01:19

Shearing Stress

2.0K
Shearing stress, denoted by the Greek letter tau (τ), is stress caused by forces acting transversely on an object. These forces create internal ones within the entity in the plane where the external forces are applied. The resultant of these internal forces is the shear in the section.
The average shearing stress can be calculated by dividing the shear by the area of the cross-section.
2.0K
Shearing Strain01:20

Shearing Strain

1.4K
The shearing strain represents a cubic element's angular change when subjected to shearing stress. This type of stress can transform a cube into an oblique parallelepiped without influencing normal strains. The cubic element experiences a significant transformation when exposed solely to shearing stress. Its shape alters from a perfect cube into a rhomboid, clearly demonstrating the effect of shearing strain. The degree of this strain is considered positive if it reduces the angle between the...
1.4K
Protein and Protein Structure02:15

Protein and Protein Structure

88.1K
Proteins are one of the most abundant organic molecules in living systems and have the most diverse range of functions of all macromolecules. Proteins may be structural, regulatory, contractile, or protective. They may serve in transport, storage, or membranes; or they may be toxins or enzymes. Their structures, like their functions, vary greatly. They are all, however, amino acid polymers arranged in a linear sequence.
A protein's shape is critical to its function. For example, an enzyme...
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Dynamical structure of entangled polymers simulated under shear flow.

Airidas Korolkovas1, Philipp Gutfreund1, Max Wolff2

  • 1Institut Laue-Langevin, 71 Rue des Martyrs, 38000 Grenoble, France.

The Journal of Chemical Physics
|August 24, 2018
PubMed
Summary

Entangled polymers exhibit complex responses to shear flow. Simulations reveal anisotropic relaxation dynamics, speeding up along flow and slowing down against it, with scale-dependent effects on the vorticity axis.

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Area of Science:

  • Polymer Physics
  • Rheology
  • Soft Matter Science

Background:

  • Understanding polymer dynamics under shear flow is crucial for material properties.
  • Current models primarily use rheological descriptions like complex viscosity.
  • A deeper insight into individual polymer chain dynamics is needed.

Purpose of the Study:

  • To investigate the non-linear response of entangled polymers to shear flow.
  • To analyze the dynamical structure of individual polymer chains during flow.
  • To provide a more complete picture beyond macroscopic rheological observables.

Main Methods:

  • Utilized a computer simulation based on an extended blob model.
  • Simulated shear flow in polymer melts and semi-dilute solutions.
  • Examined diffusion and intermediate scattering spectra under steady shear flow.

Main Results:

  • Observed anisotropic relaxation dynamics of polymer chains.
  • Dynamics accelerate along the shear flow direction.
  • Dynamics decelerate along the shear gradient direction, with scale-dependent effects on vorticity.

Conclusions:

  • The study provides new insights into polymer chain dynamics under shear.
  • Simulation results highlight the importance of chain-level dynamics in rheology.
  • Findings contribute to a more comprehensive understanding of entangled polymer behavior.