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Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour
Maurice K Payne1, Mikaela M Pyrch, Matthew Jubinsky
1Department of Chemistry, University of Iowa, Iowa City, IA 52242, USA. tori-forbes@uiowa.edu.
Abstract:
Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Different behaviour is observed in the neptunyl system due to variations in the oxo interactions.
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