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Expandability of a long C-O bond by a scissor effect in acenaphthofuran
Yasuto Uchimura1, Takuya Shimajiri, Yusuke Ishigaki
1Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. tak@sci.hokudai.ac.jp.
Abstract:
The angle strain induced by ring annulation on a spiro-type naphthofuran weakens its C(sp3)-O bond at the opposite peri-position and endows expandability, so that quite different bond lengths [1.493(3)-1.526(6) Å] are determined for the elongated C(sp3)-O bond of the corresponding spiro-acenaphthofuran derivative upon X-ray analyses of its pseudopolymorphs.
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