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Updated: Feb 6, 2026

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Published on: June 6, 2025
Experimental Study on the Laser Transmission Joining of Polystyrene and Titanium
Pin Li1,2, Jing Li3, Wensheng Tan4
1School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200000, China. lip@ujs.edu.cn.
Oxygen plasma treatment of polystyrene (PS) is crucial for laser transmission joining with titanium. Combining this with laser-treated titanium yields the highest joint strength, demonstrating improved material compatibility and bond formation.
Area of Science:
- Materials Science
- Polymer Science
- Surface Engineering
Background:
- Laser transmission joining of dissimilar materials like polystyrene (PS) and titanium presents significant challenges due to poor interfacial compatibility.
- Effective surface modification strategies are essential to overcome these limitations and achieve robust joints.
Purpose of the Study:
- To investigate and compare the effectiveness of laser treatment on titanium and oxygen plasma treatment on polystyrene for laser transmission joining.
- To determine the optimal surface treatment combination for maximizing the joint strength between PS and titanium.
- To elucidate the underlying mechanisms responsible for enhanced joint strength.
Main Methods:
- Comparative analysis of laser treatment on titanium surfaces and oxygen plasma treatment on polystyrene (PS) surfaces.
- Laser transmission joining experiments were conducted using different surface treatment combinations.
- Evaluation of joint strength through tensile failure analysis.
- Investigation of joining mechanisms using micromorphology observation, contact angle and surface free energy measurements, and X-ray photoelectron spectroscopy (XPS).
Main Results:
- Polystyrene (PS) joining with titanium is only achievable when the PS surface is treated with oxygen plasma.
- The highest joint strength, reaching 6.5 MPa, was achieved when joining laser-treated titanium with oxygen plasma-treated PS.
- Interfacial failure was observed, with fine and uniform bubbles significantly enhancing joint strength.
- Surface treatments increased surface energy and compatibility, leading to the formation of Ti-C and Ti-O chemical bonds at the interface.
Conclusions:
- Oxygen plasma treatment of PS is a prerequisite for successful laser transmission joining with titanium.
- The synergistic effect of laser-treated titanium and oxygen plasma-treated PS optimizes interfacial compatibility and bond formation.
- The formation of Ti-C and Ti-O chemical bonds is critical for achieving high joint strength in PS-titanium laser transmission joints.
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