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Updated: Feb 6, 2026

Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness
Published on: April 1, 2018
Mechanically strong polystyrene nanocomposites by peroxide-induced grafting of styrene monomers within nanoporous
Kai Li1, Junchao Huang1, Duoduo Xu1
1College of Chemistry & Molecular Sciences, Wuhan University, Wuhan, 430072, People's Republic of China.
Abstract:
Nanocellulose is a promising candidate as a "green" reinforcing nanofiller for polymer nanocomposites. Three-dimensionally nanoporous cellulose gels (NCGs) have been demonstrated to exhibit significant dispersibility and compatibilization with hydrophobic polymers. We report a simple and versatile process for the fabrication of NCG/polystyrene (PS) nanocomposites by the in situ free radical polymerization of styrene monomers within the NCG. The volume fraction of the NCG in the NCG/PS nanocomposites could be controlled from 10% to 60%. The interconnected nanofibrillar cellulose networks of the NCG were finely distributed and well preserved in the PS matrix after polymerization. Dynamic mechanical analysis revealed a remarkable reinforcement in the tensile storage modulus of the NCG/PS nanocomposites, especially above the glass transition temperature (Tg) of the PS matrix. The modified percolation model was in good agreement with the mechanical properties of the NCG/PS nanocomposites. The introduction of the NCG into the PS matrix significantly improved the flexural and tension properties of the NCG/PS nanocomposites.
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