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Preparation and Friction Force Microscopy Measurements of Immiscible, Opposing Polymer Brushes
Published on: December 24, 2014
Facile Fabrication of Concentrated Polymer Brushes with Complex Patterning by Photocontrolled Organocatalyzed Living
Chen-Gang Wang1, Chen Chen1, Keita Sakakibara2
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore, Singapore.
Abstract:
Photocontrolled surface-initiated reversible complexation mediated polymerization (photo-SI-RCMP) was successfully applied to fabricate concentrated polymer brushes with complex patterning structures. Positive-type patterned polymer brushes were obtained by photo-SI-RCMP under visible light (550(±50) nm) using photomasks. A particularly interesting finding was that negative-type patterned polymer brushes were also obtainable in a facile manner. A nonspecial UV light (250-385 nm) enabled the preparation of pre-patterned initiator surfaces in a remarkably short time (1 min), leading to negative-type patterned polymer brushes. Based on this unique selectivity between visible and UV light, the combination of two patterning techniques enabled the preparation of complex patterned brushes, including diblock copolymers, binary polymers, and functional binary polymers, without multistep immobilization of one or more initiators on the surfaces.
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