Naphthalene remediation form groundwater by calcium peroxide (CaO₂) nanoparticles in permeable reactive barrier (PRB)

This study investigated the applicability of synthesized calcium peroxide (CaO₂) nanoparticles for naphthalene bioremediation by permeable reactive barrier (PRB) from groundwater. According to the batch experiments the application of 400 mg/L of CaO₂ nanoparticles was the optimum concentration for naphthalene (20 mg/L) bioremediation. Furthermore, the effect of environmental conditions on the stability of nanoparticles showed the tremendous impacts of the initial pH and temperature on the stability and oxygen releasing potential of CaO₂. Therefore, raising the initial pH from 3 to 12 elevated the dissolved oxygen from 4 to 13.6 mg/L and the stability of nanoparticles was significantly improved around 70 d. Moreover, by increasing the temperature from 4 to 30 °C, the stability of CaO₂ declined from 120 to 30 d. The continuous-flow experiments revealed that the naphthalene-contaminated groundwater was completely bio-remediated in the presence of CaO₂ nanoparticles and microorganisms from the effluent of the column within 50 d. While, the natural remediation of the contaminant resulted in 19.7% removal at the end of the experiments (350 d). Additionally, the attached biofilm on the surface of the PRB zone was studied by scanning electron microscopy (SEM) which showed the higher biofilm formation on the pumice surfaces in the bioremediation column in comparison to the natural remediation column. The physic-chemical characteristics of the effluents from each column was also analyzed and indicated no negative impact of the bioremediation process on the groundwater. Consequently, the present paper provides a comprehensive study on the application of the CaO₂ nanoparticles in PAH-contaminated groundwater treatment.