Chemoselective Aerobic Cross-Dehydrogenative Coupling of Terminal Alkynes with Hydrosilanes by a Nanoporous Gold
Rahul D Kavthe1, Yoshifumi Ishikawa2, Indra Kusuma2
1Division of Chemistry and Materials, Shinshu University, 3-15-1 Tokida, Ueda, 386-8567, Japan.
Chemistry (Weinheim an Der Bergstrasse, Germany)
|August 31, 2018
Abstract:
Aerobic cross-dehydrogenative coupling between terminal alkynes and hydrosilanes occurred in the presence of nanoporous gold catalyst under O2 atmosphere. A variety of alkynylsilanes were synthesized in good-to-high yields and the catalyst was easily recovered and reused many times. Furthermore, the chemoselective direct silyl protection of terminal acetylenes of alkynols over the hydroxyl groups was achieved with this catalytic system.
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