Recent Progress in the Transition-Metal-Catalyzed Activation of Si-Si Bonds To Form C-Si Bonds
Peihong Xiao1, Lu Gao1, Zhenlei Song1,2
1Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu, 610064, P.R. China.
Abstract:
Disilanes possessing a Si-Si bond are unique element-element species. Transition-metal-catalyzed activation of the Si-Si bond allows many useful transformations that generate diverse organosilanes. This Minireview highlights impressive developments in this field over the past decade, with an emphasis on the formation of vinyl-, aryl-, and acylsilanes by C(sp2 )-Si bond formation as well as the formation of allyl- and alkylsilanes by C(sp3 )-Si bond formation.
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