Secondary Relaxation in Supercooled Liquid Propylene Glycol under Ultrahigh Pressures Revealed by Dielectric...

1,2-Propanediol (propylene glycol) is a well-known glassformer, which easily vitrifies under wide range of cooling rates. An interesting feature of propylene glycol is that, similar to glycerol, it retains one-mode primary relaxation (slow α process) under a wide range of external P- T conditions. It was demonstrated that the emergence of secondary (β) relaxation requires the application of very high pressures P > 4.5 GPa. In this pressure range, the observation of secondary relaxation is partially obfuscated by the presence of strong decoupling of the static (ionic) conductivity and primary relaxation (the fractional Debye-Stokes-Einstein effect). However, secondary relaxation can be unambiguously extracted from experimental data by the correlation procedure of the imaginary and real parts of the dielectric response by means of Cole-Cole plots. This is the second (after glycerol) example of observation of Johari-Goldstein relaxation under ultrahigh pressures P > 2 GPa.