Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

Grace B Panetti1, Jerome R Robinson, Patrick J Carroll

  • 1P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA. pwalsh@sas.upenn.edu schelter@sas.upenn.edu.

Related Concept Videos

Hydrogen Bonds00:26

Hydrogen Bonds

Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
133.9K
Hydrogen Bonds01:04

Hydrogen Bonds

A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
14.7K
Conditions on Early Earth02:06

Conditions on Early Earth

Around 4 billion years ago, oceans began to condense on earth while volcanic eruptions released nitrogen, carbon dioxide, methane, ammonia, and hydrogen into the primordial atmosphere. However, organisms with the characteristics of life were not initially present on earth. Scientists have used experimentation to determine how organisms evolved that could grow, reproduce, and maintain an internal environment.
101.7K
Acceleration due to Gravity on Earth01:21

Acceleration due to Gravity on Earth

According to Newton's law of gravitation, the gravitational force on a body is proportional to its mass. According to Newton's second law of motion, the acceleration produced by an external force is inversely proportional to the force. Hence, the acceleration of an object under an external force of gravitation is independent of its mass.
The acceleration of an object close to the Earth, because of the Earth's gravitational pull, is called the acceleration due to gravity. It is...
12.1K
Apparent Weight and the Earth's Rotation01:28

Apparent Weight and the Earth's Rotation

Since all objects on the Earth's surface move through a circle every 24 hours, there must be a net centripetal force on each object, directed towards the center of that circle. The points of the north and south poles are the only exception to this rule.
For an object on the Earth's equator, the net centripetal force that accounts for its rotation is the Earth's pull towards its center, or the weight minus the normal force that prevents it from piercing into the Earth's surface....
4.1K
Variation in Acceleration due to Gravity near the Earth's Surface01:20

Variation in Acceleration due to Gravity near the Earth's Surface

An object's apparent weight is its weight measured by a spring balance at its location. It is different from its true weight, the force with which the Earth pulls it, because of the Earth's rotation. Mathematically, an object's apparent weight equals its true weight minus the centripetal force that keeps it in a circular motion along with the Earth's surface every 24 hours.
The difference between the true and apparent weights is proportional to the square of the Earth's...
2.9K