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Calix[6]arene-based atropoisomeric pseudo[2]rotaxanes

Carmine Gaeta1, Carmen Talotta1, Placido Neri1

  • 1Dipartimento di Chimica e Biologia " A. Zambelli", Università di Salerno, Via Giovanni Paolo II 132, 84084 Fisciano (Salerno), Italy.

Beilstein Journal of Organic Chemistry
|September 12, 2018
PubMed
Summary

This study reports atropoisomeric pseudorotaxanes formed by threading a calixarene wheel with ammonium axles. The distinct conformations of the calixarene wheel lead to kinetic and thermodynamic isomers.

Keywords:
atropoisomerscalixareneconformationpseudorotaxanesocial isomerism

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