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  2. Ultrafine Mo-doped Sno
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Ultrafine Mo-doped SnO

Yanli Chen1, Dongtao Ge, Jie Zhang

  • 1College of Materials, Xiamen University, Siming South Road, Xiamen, Fujian, China. gedt@xmu.edu.cn yzhang@xmu.edu.cn.my.

Nanoscale
|September 12, 2018

View abstract on PubMed

Summary
This summary is machine-generated.

Researchers developed Mo-doped SnO2 nanoparticles to overcome structural decay in tin-based anodes for lithium-ion batteries (LIBs). This innovation enhances battery performance and longevity, offering a promising solution for high-capacity energy storage.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Tin-based materials are promising for high-capacity lithium-ion battery (LIB) anodes due to cost and energy density.
  • Severe structural decay during cycling limits the performance and lifespan of traditional tin anodes.
  • Developing stable and high-performance anode materials is crucial for advancing LIB technology.

Purpose of the Study:

  • To synthesize and characterize molybdenum-doped tin dioxide (SnO2) nanostructures for improved LIB anode performance.
  • To investigate the electrochemical behavior and long-term stability of Mo-doped SnO2 nanoparticles.
  • To develop a binder-free, free-standing anode using Mo-doped SnO2 integrated into carbon nanofibers.

Main Methods:

  • Facile hydrothermal synthesis of Mo-doped SnO2 nanostructures.
  • Electrochemical testing to evaluate capacity, cyclability, and kinetics.
  • Electrospinning and in-situ reduction to fabricate free-standing nanofiber membrane anodes.
  • Main Results:

    • Mo-doped SnO2 nanoparticles exhibited enhanced electrochemical kinetics and cyclability, retaining a reversible capacity of 670 mA h g-1 after 700 cycles.
    • The nanostructure fragmentation into ultrafine, fracture-resistant particles contributed to improved stability.
    • The free-standing nanofiber membrane anode demonstrated comparable performance to conventional slurry-coated electrodes without binders or current collectors.

    Conclusions:

    • Mo-doped SnO2 nanoparticles offer a viable solution to the structural decay issues in tin-based anodes for LIBs.
    • The developed free-standing anode architecture presents a simplified and efficient approach for next-generation LIBs.
    • This research highlights the potential of nanostructured, doped metal oxides for high-performance energy storage applications.