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Constructing POSS and viologen-linked porous cationic frameworks induced by the Zincke reaction for efficient CO
Guojian Chen1, Xiaohui Huang1, Yadong Zhang1
1School of Chemistry and Materials Science, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, China. gjchen@jsnu.edu.cn longzhouyangfat@163.com.
Abstract:
POSS and viologen-linked porous cationic frameworks (V-PCIF-X, X = Cl, Br) are constructed via the Zincke reaction between octa(aminophenyl)silsesquioxane and viologen linkers. The typical V-PCIF-Br has a high surface area with abundant ionic sites, micro-/mesopores and Si-OH groups, serving as an efficient porous adsorbent and metal-free catalyst for simultaneous CO2 capture and conversion.
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