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Updated: Feb 5, 2026

Flash Infrared Annealing for Perovskite Solar Cell Processing
Published on: February 3, 2021
Ag@SiO₂ Core-shell Nanoparticles Embedded in a TiO₂ Mesoporous Layer Substantially Improve the Performance of
Bao Wang1, Xiangyu Zhu2, Shuhan Li3
1School of Science, Wuhan University of Technology, Wuhan 430070, China. 1174828021@whut.edu.cn.
Abstract:
In this study, Ag@SiO₂ nanoparticles were synthesized by a modified Stöber method for preparing the TiO₂ mesoporous layer of carbon counter electrode-based perovskite solar cells (PSCs) without a hole transporting layer. Compared with normal PSCs (without Ag@SiO₂ incorporated in the TiO₂ mesoporous layer), PSCs with an optimal content of Ag@SiO₂ (0.3 wt. % Ag@SiO₂-TiO₂) show a 19.46% increase in their power conversion efficiency, from 12.23% to 14.61%, which is mainly attributed to the 13.89% enhancement of the short-circuit current density, from 20.23 mA/cm² to 23.04 mA/cm². These enhancements mainly contributed to the localized surface Plasmon resonance effect and the strong scattering effect of Ag@SiO₂ nanoparticles. However, increasing the Ag@SiO₂ concentration in the mesoporous layer past the optimum level cannot further increase the short-circuit current density and incident photon-to-electron conversion efficiency of the devices, which is primarily ascribed to the electron transport pathways being impeded by the insulating silica shells inside the TiO₂ network.
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