Related Experiment Video
Updated: Feb 5, 2026

10:49
Laboratory-determined Phosphorus Flux from Lake Sediments as a Measure of Internal Phosphorus Loading
Published on: March 6, 2014
17.8K
Phosphorus Recovery by Methods Beyond Struvite Precipitation
Summary
Recovering phosphorus as calcium phosphate from water resource recovery facilities offers a cost-effective alternative to struvite recovery. This method provides valuable fertilizer feedstock and industrial materials, addressing phosphorus scarcity.
Area of Science:
- Environmental Engineering
- Chemical Engineering
- Resource Recovery
Background:
- Unintentional phosphate precipitation in water resource recovery facilities (WRRFs) creates operational issues.
- Global phosphorus scarcity and eutrophication from P discharge necessitate P recovery strategies.
- Current P recovery often focuses on struvite, which may not always be cost-effective.
Purpose of the Study:
- To review the potential of calcium phosphate recovery as an alternative to struvite recovery.
- To evaluate calcium phosphate as a fertilizer feedstock and for industrial applications.
- To propose a strategic approach for regional reclaimed phosphate reserves.
Main Methods:
- State-of-the-art review of phosphorus recovery technologies.
- Analysis of cost-effectiveness for calcium phosphate versus struvite recovery.
- Assessment of calcium phosphate's suitability for fertilizer and industrial use.
Main Results:
- Calcium phosphate recovery can be more cost-effective than struvite recovery, especially when fertilizer prices are low.
- Calcium phosphate offers broader industrial applications due to its similarity to mined phosphate rock.
- A strategic approach can secure economical future phosphorus supplies.
Conclusions:
- Calcium phosphate recovery presents a viable and potentially more economical alternative for phosphorus recovery at WRRFs.
- This approach contributes to resource circularity and addresses phosphorus scarcity.
- Developing regional reclaimed phosphate reserves is crucial for sustainable phosphorus management.
Related Concept Videos
The Phosphorus Cycle
44.0K
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
44.0K
Precipitation of Ions
30.3K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
30.3K
Precipitation and Co-precipitation
4.3K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
4.3K
Precipitation Reactions
65.5K
In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound – the precipitate. The reaction occurs when oppositely charged ions in solution overcome their attraction for water and bind to each other, forming a precipitate that separates out from the solution. Since such reactions involve the exchange of ions between ionic compounds in aqueous solution, they are also referred to as double displacement, double replacement, exchange reactions, or...
65.5K
Precipitation Titration: Endpoint Detection Methods
6.0K
In argentometric precipitation titrations, endpoints can be detected visually by the Mohr, Volhard, and Fajans methods. In the Mohr method, adding a soluble chromate indicator gives an initial yellow color to the analyte solution. As the titrant is added, the first excess of silver ions forms a red silver chromate precipitate, marking the endpoint. The solution pH should be maintained at about 8 by adding solid CaCO3.
In the Volhard method, a standard excess of AgNO3 is first added to the...
In the Volhard method, a standard excess of AgNO3 is first added to the...
6.0K
Precipitation Processes
6.3K
The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
6.3K

