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Related Concept Videos

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
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Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Structures of Solids02:22

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Updated: Feb 5, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State

Tetsuya Asano1, Akihiro Sakai1, Satoru Ouchi1

  • 1Technology Innovation Division, Panasonic Corporation, 1006 Kadoma, Kadoma-shi, Osaka, 571-8508, Japan.

Advanced Materials (Deerfield Beach, Fla.)
|September 15, 2018
PubMed
Summary

New lithium halide materials show high conductivity and stability, making them promising for large-scale solid-state batteries. These materials offer excellent performance without extra coatings, advancing battery technology.

Keywords:
all-solid-state batterieshalide solid electrolyteslithium-ion conductorssolid-state ionicsyttrium halides

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Batteries

Background:

  • All-solid-state batteries (ASSBs) require solid electrolytes with high ionic conductivity, mechanical stability, and chemical inertness.
  • Current solid electrolyte options, such as sulfides and oxides, face challenges in large-scale manufacturing and performance.

Purpose of the Study:

  • To discover and characterize novel lithium halide materials for ASSB applications.
  • To evaluate the electrochemical performance and stability of these new materials.

Main Methods:

  • Synthesis and characterization of new lithium halide compounds (Li3YCl6 and Li3YBr6).
  • Measurement of ionic conductivity using electrochemical impedance spectroscopy.
  • Fabrication and testing of bulk-type ASSB cells with LiCoO2 cathodes.

Main Results:

  • Li3YCl6 and Li3YBr6 exhibit high lithium-ion conductivity (>1 mS cm-1 at room temperature) in cold-pressed powders.
  • These materials demonstrate high deformability, chemical, and electrochemical stability.
  • ASSB cells using these halides achieved high coulombic efficiencies (94%) with LiCoO2 cathodes without coatings.

Conclusions:

  • Lithium halide salts represent a new class of promising solid electrolytes for ASSBs.
  • The discovered materials offer a viable alternative to sulfide and oxide electrolytes for scalable battery applications.